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Posted by Steven Hays on Oct-27-2003 18:48:

Balance This Equation (Answer solved Biyatches)

Okay, Neither my instructor or the students, a small class mind you, cannot figure this equation out. It might not be able to be solved, but there might as well be one. Anyone want to give this a shot???

Equation:

Cu(s) + HNO3(aq) --> Cu(NO3)2(aq) + NO(g) + H2O(l)

Answer:

3Cu(s) + 8HNO3(aq) --> 3Cu(NO3)2(aq) + 2NO(g) + 4H2O(l)

* I don't know how to do subscripts here, but you get the point!


peace.

Steve


Posted by dj_mdma on Oct-27-2003 18:59:

Copper + Nitric Acid = Coppor Nitrite + Nitric Oxide + Water

I think the formula for Nitric Acid is wrong, isn't it H2N03? I'm prolly wrong, i only got a C for A Level Chemistry

and if your teacher can't work it out, then you're definately screwed


Posted by DjSimonB on Oct-27-2003 22:54:

I'd try it, but I'm so fucking sick of Chem after how bad it was last year, I just wanna forget about it (and I'm a lazy bam )

mdma: the formula for nitric acid that he had is correct, HNO3


Posted by Massive84 on Oct-27-2003 22:59:

I think it is H3NO2

Because Hydrogen has 2 postive ionen H2+ (spelled right) and those 2 go to NO3-..and the 3 goes to H2..

i remember thats how it worked..

so H3NO2

been sooo long since i had chmestry, kinda miss it


Posted by Turbonium on Oct-27-2003 23:14:

on it gimme a sec


Posted by Turbonium on Oct-27-2003 23:18:

is it acidic or basic solution?

nm acidic


Posted by Floorfiller on Oct-27-2003 23:22:

can't you do some kind of trick where you add an OH and H2O to the formula to help balance it like this??

CU + 3HNO3 + H20 -------> CU(NO3)2 + NO + 2H20 + OH

although this is balanced...i don't think that's right (its been tooooo long hehehe), but don't you have to do something like that??


Posted by Turbonium on Oct-27-2003 23:25:

quote:
Originally posted by Floorfiller
can't you do some kind of trick where you add an OH and H2O to the formula to help balance it like this??

CU + 3HNO3 + H20 -------> CU(NO3)2 + NO + 2H20 + OH

although this is balanced...i don't think that's right, but don't you have to do something like that??


that's exactly what u do, assign oxidation numbers, etc.

I got an answer, but it's screwy, and I get this stuff right 99% of the time. r u sure u typed the eqn in right? double check it, i'll recheck mine again


Posted by Floorfiller on Oct-27-2003 23:29:

quote:
Originally posted by Floorfiller
can't you do some kind of trick where you add an OH and H2O to the formula to help balance it like this??

CU + 3HNO3 + H20 -------> CU(NO3)2 + NO + 2H20 + OH

although this is balanced...i don't think that's right (its been tooooo long hehehe), but don't you have to do something like that??



Left Side:

CU = 1

H = 5

N = 3

O = 10

Right Side:

CU = 1

H = 5

N = 3

O = 10


i'm pretty sure that my equation is balanced, but that doesn't mean that i did it right hehehe...


Posted by Steven Hays on Oct-27-2003 23:31:

quote:
Originally posted by Turbonium
that's exactly what u do, assign oxidation numbers, etc.

I got an answer, but it's screwy, and I get this stuff right 99% of the time. r u sure u typed the eqn in right? double check it, i'll recheck mine again


Yeah, its typed in right, just I don't know if its possible. Trying to conclude whether or not it is.


Posted by Turbonium on Oct-27-2003 23:32:

I get the initial part correct, but restoring it to normal eqn yield incorrect result, weird...

3Cu + 8H(+) + 2NO3(-) ---> 3Cu(2+) + 2NO + 4H2O

full eqn (if I did it right, which according to this, I didn't):

3Cu + 2HNO3 + 6H(+) ---> 3Cu(NO3)2 + 2NO + 4H2O


Posted by Steven Hays on Oct-27-2003 23:34:

THis is a stinker, and I don't know enough of chemistry to understand the oxidation method...


Posted by Floorfiller on Oct-27-2003 23:35:

quote:
Originally posted by Evan Almae
THis is a stinker, and I don't know enough of chemistry to understand the oxidation method...


your teacher should...what level chemistry are you in??


Posted by Steven Hays on Oct-27-2003 23:35:

quote:
Originally posted by Floorfiller
your teacher should...what level chemistry are you in??


LOL, Intro! This is for extra credit too, just cause the teach can't finger it out!


Posted by Floorfiller on Oct-27-2003 23:37:

quote:
Originally posted by Evan Almae
LOL, Intro! This is for extra credit too, just cause the teach can't finger it out!


well you'll be getting to this oxidation stuff...i'm sure its in your book. it looks like your teacher is just an asshole and gave you guys an equation that he shouldn't have yet hehehe...


Posted by Turbonium on Oct-27-2003 23:42:

Here are the oxid. numbers, just to accompany you if ur looking up oxid. numbers in the text. They're easy, trust me.

In chronological order...

Cu
Cu : 0

HNO3
H : +1
N : +5
O : -2

Cu(NO3)2
CU : +2
N : +5
O : -2

NO
N : +2
O : -2

H2O
H : +1
O : -2


Posted by Floorfiller on Oct-27-2003 23:46:

quote:
Originally posted by Turbonium
Here are the oxid. numbers, just to accompany you if ur looking up oxid. numbers in the text. They're easy, trust me.

In chronological order...

Cu
Cu : 0

HNO3
H : +1
N : +5
O : -2

Cu(NO3)2
CU : +2
N : +5
O : -2

NO
N : +2
O : -2

H2O
H : +1
O : -2


you seem to remember better than i do...what is the rule? i saw that you added H+ and H2O and no OH?? don't you add OH to balance out the oxygens or something? i don't know...its been a good 6 years since AP chem in sophomore year in highschool hehehe...


Posted by Turbonium on Oct-27-2003 23:47:

quote:
Originally posted by Floorfiller
you seem to remember better than i do...what is the rule? i saw that you added H+ and H2O and no OH?? don't you add OH to balance out the oxygens or something? i don't know...its been a good 6 years since AP chem in sophomore year in highschool hehehe...


You only add OH if it's a basic solution. It's acidic though (HNO3 is nitric acid).


Posted by Floorfiller on Oct-27-2003 23:49:

quote:
Originally posted by Turbonium
You only add OH if it's a basic solution. It's acidic though (HNO3 is nitric acid).


thats right...good call...lemme try this again hehehe...


Posted by J.L. on Oct-27-2003 23:50:

check my answer below

|
|
v


Posted by Floorfiller on Oct-27-2003 23:53:

well kewlness is probably right hehehe...this is what i got

CU + 3HNO3 + H ------> CU(NO3)2 + NO + 2H2O

mine looks simple so there ne ner ne ner hehehe...


Posted by Turbonium on Oct-27-2003 23:56:

quote:
Originally posted by kewlness
The correct answer
5Cu + 12HNO3 -> 5Cu(NO3)2 + 2NO + 6H2O

How I did it:
assign the unknown coefficients as unknowns x1,x2,x3,x4,x5
x1Cu + x2HNO3 -> x3Cu(NO3)2 + x4NO + x5H2O

Now you know that
x1 - x3 = 0 for Copper
x2 - 2x5 = 0 for Hydrogen
3x2 - 6x3 - x4 -x5 = 0 for Oxygen
x2 - 2x3 - x4 = 0 for Nitrogen

Solving for the system of equations (i used linear algebra but you can use any method you want), I got the solutions:

x1= 5/6 t
x2 = 2t
x3= 5/6 t
x4= 1/3 t
x5= t

where t is a parameter
Now you have to choose a value t so that x1,x2,x3,x4,x5 are integers (1,2,3,4,5,6, etc...) while still being in the lowest denominator... The number that fits this category is where t=6

so therefore x1 = 5, x2 = 12 x3 = 5 x4 = 2 x5 = 6

I win. Go get that bonus mark tommorow


Sorry but your answer is incorrect. 36 oxygen on left, 38 on right.


Posted by Floorfiller on Oct-27-2003 23:57:

quote:
Originally posted by Turbonium
Sorry but your answer is incorrect. 36 oxygen on left, 38 on right.


yeah that must mean that i win hehehehe


Posted by Steven Hays on Oct-27-2003 23:58:

quote:
Originally posted by Turbonium
Sorry but your answer is incorrect. 36 oxygen on left, 38 on right.


I was just about to say that! Nice try though! Thanks everyone for helping by the way! Didn't want to leave that unsaid, your help is much appreciated!


Posted by J.L. on Oct-27-2003 23:58:

hmm.. let me re-do that.. i think i screwed up somewhere... go linear algebra


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