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Posted by Turbonium on Oct-13-2003 22:17:

chem

What does the Lewis Dot Diagram for PBrF4 look like? (phosphorous bromine tetrafluoride - I think thats what it's called)


Posted by drizzt81 on Oct-13-2003 22:19:

Re: chem

quote:
Originally posted by Turbonium
What does the Lewis Dot Diagram for PBrF4 look like? (phosphorous bromine tetrafluoride - I think thats what it's called)
I assume P is main group 5, it MIGHT look like this:

code:
Br \ F - P - F F/ \F


Posted by Turbonium on Oct-13-2003 22:28:

K that's what I figured. But is the molecule polar? All the bonds are polar (En difference greater than or equal to 0.4). But does the fact that the Br is different that the 4 fluorides make it a difference enough to make it polar? If all 5 were fluorides, it obviously wouln't be polar.

En of P = 2.19
En of F = 3.98
En of Br = 2.96


Posted by drizzt81 on Oct-13-2003 22:35:

quote:
Originally posted by Turbonium
K that's what I figured. But is the molecule polar? All the bonds are polar (En difference greater than or equal to 0.4). But does the fact that the Br is different that the 4 fluorides make it a difference enough to make it polar? If all 5 were fluorides, it obviously wouln't be polar.

En of P = 2.19
En of F = 3.98
En of Br = 2.96


i am NOT the authority on this, but i'd say it is. If you think about it:
You have this lonely Br atom on one end, which isn't all that EN, then these four MONSTERS of EN-ity on the other side, who pull like some crazy mofo's on those e-'s?

anyway, ask someone who knows their stuff, it's been 2 1/2 years for me.. i can tell you all about silicon crystals though.. if you care to know


Posted by blazed it on Oct-14-2003 00:50:

gibberish.... LOL


god i hate chemistry


Posted by Mako on Oct-14-2003 00:53:

Yes it is polar, when thinking about polarity, think vectors.

Edit: sorry i didn't pay attention to the whole molecule . So yeah it will because, there are 4 fluorines (most electronegative F = 4.0) while bromine is less electronegative. The fluorines will pull electrons towards themselves from other atoms, making P and ultimately Br (which are both less electronegative) slightly more positive, giving a small charge separation.


Posted by drizzt81 on Oct-14-2003 00:58:

quote:
Originally posted by Mako
Yes it is polar, when thinking about polarity, think vectors.

Edit: sorry i didn't pay attention to the whole molecule . So yeah it will because, there are 4 fluorines (most electronegative F = 4.0) while bromine is less electronegative. The fluorines will pull electrons towards themselves from other atoms, making P and ultimately Br (which are both less electronegative) slightly more positive, giving a small charge separation.


but the other atoms are Fluorine, which is even more EN.

n/m


Posted by Mako on Oct-14-2003 00:59:

quote:
Originally posted by drizzt81
but the other atoms are Fluorine, which is even more EN.

n/m


err.. you didn't read my edit?


Posted by Mako on Oct-14-2003 01:00:

quote:
Originally posted by Mako
err.. you didn't read my edit?


ohh n/m lol!


Posted by drizzt81 on Oct-14-2003 01:08:

quote:
Originally posted by Mako
ohh n/m lol!
i gather you did not read mine ;P


Posted by Mako on Oct-14-2003 01:10:

quote:
Originally posted by drizzt81
i gather you did not read mine ;P



Posted by zarathustra on Oct-14-2003 01:31:

Looks polar to me, although Chem was a looooong time ago.


Posted by drizzt81 on Oct-14-2003 01:32:

quote:
Originally posted by zarathustra
Looks polar to me, although Chem was a looooong time ago.
hehe [from the religion thread] since we all believe it's polar, it has to be ;P


Posted by Mako on Oct-14-2003 01:34:

quote:
Originally posted by drizzt81
hehe [from the religion thread] since we all believe it's polar, it has to be ;P



lol...in a parallel universe it might not be

imagine the consequences...like hmmmm...tiesto spinning scooter (even though he's pretty close to that stage..


Posted by drizzt81 on Oct-14-2003 01:37:

quote:
Originally posted by Mako
lol...in a parallel universe it might not be

imagine the consequences...like hmmmm...tiesto spinning scooter (even though he's pretty close to that stage..
well everytime he spins "Push - Strange World" he might almsot be spinning a scooter track Weekend *yuck*


Posted by Mako on Oct-14-2003 01:40:

quote:
Originally posted by drizzt81
well everytime he spins "Push - Strange World" he might almsot be spinning a scooter track Weekend *yuck*


or "how much is that fish" or fuck the millenium..:S


Posted by drizzt81 on Oct-14-2003 01:47:

quote:
Originally posted by Mako
or "how much is that fish" or fuck the millenium..:S
or "Endless Summer"..

I think scooter wouldn't be half-bad if they fot rid of this blonde idiot that is too full of himself.. take out HIS voice from all tracks and some of them would be fun


Posted by Mako on Oct-14-2003 01:50:

quote:
Originally posted by drizzt81
or "Endless Summer"..

I think scooter wouldn't be half-bad if they fot rid of this blonde idiot that is too full of himself.. take out HIS voice from all tracks and some of them would be fun


yeah true...those lyrics sounds like as if they've been written by a crackhead.


Posted by drizzt81 on Oct-14-2003 01:57:

quote:
Originally posted by Mako
yeah true...those lyrics sounds like as if they've been written by a crackhead.
"Party people....RAAAAAAAAVERS.... can you smell/ feel it.... love is in teh AAAAAAAAAAir.. it's time for summmer.. and EEEEEEENdless summmeeerrr.."

laf


Posted by Mako on Oct-14-2003 01:58:

quote:
Originally posted by drizzt81
"Party people....RAAAAAAAAVERS.... can you smell/ feel it.... love is in teh AAAAAAAAAAir.. it's time for summmer.. and EEEEEEENdless summmeeerrr.."

laf


*barf*

hmm still trying to ID that song in that cassius set... such a good song *sniff* anyone on TA can relate to that song...


Posted by drizzt81 on Oct-14-2003 02:13:

quote:
Originally posted by Mako
*barf*

hmm still trying to ID that song in that cassius set... such a good song *sniff* anyone on TA can relate to that song...
um should i look into the tracklist/ id forum?


Posted by Mako on Oct-14-2003 02:18:

got the description here:

http://www.tranceaddict.com/forums/...threadid=128040

last post


Posted by drizzt81 on Oct-14-2003 02:20:

quote:
Originally posted by Mako
got the description here:

http://www.tranceaddict.com/forums/...threadid=128040

last post


sorry nope.


Posted by Mako on Oct-14-2003 02:23:

quote:
Originally posted by drizzt81
sorry nope.


bahhh... i want! ffs


Posted by Turbonium on Oct-14-2003 03:08:

Ok I need your help on this big time... simple question tho. Do any of the following have resonant structures?:

PO3 3-
PO4 3-
BrO2 -
BrO3 -

I drew the structures for each and none turned out to be resonant, but the question asks "draw all resonant structures for those that apply". So I'm thinking at least one of them should have been.


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