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You can get decent results by using the center channel extractor in Adobe Audition (or something similar) to create a non-vocals version, then use the phase-invert approach mentioned above to isolate the vocals from the original (i.e., phase invert the original and non-vocals version to cancel out everything except the vocals). You may have to make both versions mono in order to minimize the remaining center channel frequencies.
I've also been able to isolate vocals using spectral editing (noise profiling) in Izotope RX, but didn't spend enough time to get great results.
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