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If you're just starting out, I'd advise to use the Pro 5 rather than FM7, as it is easier to understand how the sounds are built.
Start by using saw waves, as they have more harmonics (i.e. they have more frequencies making up a single sound). This will naturally give a fatter sound to start with.
Reverb is a spatial effect, simulating what your sound source might sound like in different rooms (e.g. a small church, a large concert hall etc.) Reverb can add space to a sound, but it can make the sound lose definition. For your fat lead, try adding a little until you can hear the difference, but not too much.
As for the other parameters (detuning, LFO amount) just try starting with a little and adding more and more. You should be able to hear the difference made and when it gets too much, just reduce it a bit again and leave it at that. Part of the joy (and skill) of synth programming is to adjust everything until it sounds good and fits in your track nicely.
A final point, IMO you should use your ears for comparing sounds, don't examine the waveforms. It's about how it sounds, not how it looks 
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