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You can partition and boot different versions of XP if you have the XP CD.
Just go into your BIOS, set the first boot device to CD-ROM, put the XP CD in your drive, and press reset!
Once you boot from the CD there's an option to create more partions, and install windows. You can even have multiple versions of XP installed on the same partition, tho you'll get promted everytime which operating system you want to boot from during startup.
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