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i'd recommend virtualdubMOD
it handles VBR audio streams, whereas virtualdub will re-encode the audio stream from VBR to CBR (which knocks the a-v sync completely outta wack).
http://virtualdubmod.sourceforge.net/
oh yeh, i burnt 717MB onto a cd-rw just before so give it a go 
nero will pop up the box where it'll tell ya that it has to finalize the disc, just click ok and you should be on your way.
although with overburn, nero does have this warning that the disc might not work at all, so its best to play around with an rewriteable first, unless you're a fan of cd coasters 
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