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PWM is, as mentioned, modulating (changing) the pulse width.
think of a normal square wave. with no PWM, you've got 50% full positive cycle, and 50% full negative cycle.
as you modulate the width of the pulse, you end up with a smaller and smaller.shorter positive duty and a bigger/longer negative duty - which can make the sound thinner if kept static, or add a bit of atonal chorusing (if that makes sense - you'll know it when you hear it). if your synth will let you pwm by envelope you can get interesting effects by setting the attack and decay to short times as you might do with a VCF on a bass sound. hope this helps, sorry if its complete crap. 
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