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My music theory is pretty rusty, and I had to dig around for this information.
Pitches that are the same but notated differently (A# = Bb, D# = Eb, etc.) are called 'enharmonic'. (I really forgot this term...)
I'm not entirely sure why F# is used rather than Gb, apart from F# being the first sharp, and Gb being somewhere in the middle (5th or so?).
Perhaps someone with a better knowledge of music theory can shed some light on this.
(It's kind of embarassing for me to not know this, actually, especially since I still play a musical instrument.)
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