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here's a good article on mastering/normalizing on the reason website.
LINK
BUT before you start normalizing, as DJ Thy said, it is ESSENTIAL that the level you record at is as hot as possible (without clipping) before you start normalizing. Normalizing is the last step in the production process and should never be used to correct recording levels. Reason being, if you record digitally at too low a level and then boost the whole thing, you will either get a lot of noise, or a lot of nothingness. say for example you record at -20dB, and then normalize the whole wave to 0dB...that 20 dB boost is coming from nowhere. what you are doing then is only raising the noise floor in which you recorded from, and boosting the volume of everything. not a very good technique.
to reiterate again, to record properly, check your levels at all the stages (but most importantly the levels in your computer as that is what you are recording onto). for example, if you are recording with soundforge, (under special, transport, reocord or just ctrl+r) you can see the levels you are recording at. then either boost the line-in from your soundcard, or the line-out from your mixer. what you should look for is the loudest passage of your mix (say right after the buildup when everything hits again) and make SURE that it doesn't go red. digital distortion (aka saturation) is irreversible and is not something you want.
then to master properly, read the article i linked above.
one last thing to B_K, you don't want to record from the monitor out, i suspect it should be of lower quality then the master out. ideally there should be a record out, but since you say there isn't, go for the master out. monitor out is for that exactly, just for monitoring. and for adjusting line-in levels, try go control panel and then sound, there should be a simple windows mixer in there somewhere. ur soundcard should also have one.
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