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Your best bet is to get an acoustic guitar multisample, and use a plugin like NI's Guitar Rig to get all the pedals, speaker simulation, and other effects. You can try to synthesize it, but I've never had much success in that area. Samples are not hard to find; Spectrasonics has lots of guitar libraries, Kontakt comes with several acoustic guitars, etc.
Guitars are like piano in a sense though - even if you recreate the instrument perfectly, it won't sound authentic unless it's either played by a human or you carefully adjust every single note and velocity to "humanize" it. Sometimes you don't need that authenticity - all depends on the track. If that is what you want, though, you'll get better results with a crappy sample and a lot of dynamic/rhythmic variation than you will with a great sample played mechanically.
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