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Yes you can, very easily.
Plug the iPod in and go into iTunes, it will appear there, make sure you click no when it asks you if you want to switch to this iTunes libary. Then on the ipod, right click > ipod options > tick manually manage playlists.
You can also get a program, there are thousands out there, check ipodlounge, I belive they have some sort of software listing that will help you.
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