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Actually, if you have two copies that are EXACTLY the same but one has no vocals, then it would be quite easy to align them properly and invert one waveform to isolate the acapella.
Unfortunately it is never that simple. You might have two tracks that *sound* identical except for the vocals, but in reality they will each have gone through several processes that significantly change the waveform during or after the mixdown (compressors, stereo expanders, tubes, brickwall levellers, reverb, etc.)
At the very least, both versions will have gone through a mastering compressor/leveller, and think about the result of that - when the vocals are compressed with the rest of the track, it will lower the overall volume of the other instruments, and not in a linear fashion that you can compensate for when you try to do your inversion "rip". The waveform of the "dub" version is NOT identical to the sum of the dub and the acapella, therefore the sum of the vocal version and inverted dub will not give you the acapella. Compression, stereo expansion, and other processes that change the track this way are NOT reversible.
Thus, in all seriousness, it is simply not possible to cleanly rip a vocal from a track, no matter what tools or materials you have at your disposal. You might be able to get a version that's "good enough" for the typical audience, but keen listeners (especially other producers) will be able to tell the difference very easily.
And do people really need to be reminded that even if it could be done successfully, it is still completely unethical? Trying to rip vocals from a full track goes far beyond the realm of harmless sampling and editing - you're doing this with the express goal of taking credit for somebody else's hard work.
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