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Well aside from the Mall, there's Hiawatha Falls since you're into nature. Summit Ave. in St. Paul is pretty cool - victorian houses and cafes all over the place.
There are a ton of art galleries - I'm partial to the Minneapolis Art Institute, but the Walker is really cool too, and they have a huge outdoor sculpture garden. Great theater district too - second-largest in the US after NYC.

Beyond that, there are a bunch of parks and good bars all over the metro area. It's definitely an under-rated city.
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