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here you can find probably the most complete guide to synthesis
http://www.soundonsound.com/sos/allsynthsecrets.htm
It's a lot of reading (seriously, it's good to just print it on paper and read during some spare time) but eventually you'll gain more knowledge about overall synthesis aspect.
I also like this video (720p) - it's an In the studio session with Chris Lake
http://www.youtube.com/watch?v=h_r-...player_embedded
it's an analysis of his great (the best ?) track - If you knew. That that covers very wide range of frequencies so mixing it was quite a tough task. Chris analises every channel - very informative video and my personal best video from Future Music - In the studio series.
About layering - hmm it's pretty hard to give some hints but mine are:
1. Layer the sounds that cover different frequencies (ie. some Hi Pad and Low Pad)
2. Layer long release sounds (pads, strings) with short ones (ie. guitar plucks)
3. Layer sounds that cover same frequencies but prepare for compression, sometimes heavy EQing and overall results can be random.
Also, you can layer sounds that have similar frequencies but have different panorama (ie. one sound is mono, the other is stereo). Result ? Richer sound.
4. Layer sounds coming from different softsynth. Developers do some serious audio manipulations so most soft synths have their own character. Supersaw from synth A sounds different than supersaw from synth B - so at the end you may get sound that is more full, rich etc.
5. Ahh, when I layer sounds I disable their internal Reverb , Delay settings. I add reverb, delay (if I want too) at the "end of the chain" (after these two sounds are combined). Thanks to this, the sounds will be better glued.
Maybe not strictly related with trance but personally I love layering short sounds (plucks, bells, piano hits, guitar plucks) with long pads. Quite often it totally changes the character of the sound.
And probably the most general tip - EQ and Compressor are your biggest friends. You can use some tape saturation plugins (ie. freeware FerricTDS is pretty nice - it nicely smoothens the sound).
The tip with third party presets is also good. Personally I dont like to create presets during the arrangement. I can get quickly out of inspiration. That's why i think it's good to have personal database of presets (created BEFORE composing) you like. I like to create my own presets, well I sell them too, but I also buy quite a lot of third party presets. Why ? Well, I usually spend one, two evenings to scroll through every preset and pick those I like the most, and combine them into one big, personal favourites presets soundbank. Then I can focus on arrangement.
In my opinion finding the correct sound can be pretty tough (and time consuming task) task, that's why I don't like to navigate through hundreds of sounds. I prefer having favourite soundbank with 100-200 presets rather than factory soundbank of 1000 presets + additional 23452 third party presets 
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