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Turbonium
What does the Lewis Dot Diagram for PBrF4 look like? (phosphorous bromine tetrafluoride - I think thats what it's called)
drizzt81
quote:
Originally posted by Turbonium
What does the Lewis Dot Diagram for PBrF4 look like? (phosphorous bromine tetrafluoride - I think thats what it's called)
I assume P is main group 5, it MIGHT look like this:
code:
Br \ F - P - F F/ \F
Turbonium
K that's what I figured. But is the molecule polar? All the bonds are polar (En difference greater than or equal to 0.4). But does the fact that the Br is different that the 4 fluorides make it a difference enough to make it polar? If all 5 were fluorides, it obviously wouln't be polar.

En of P = 2.19
En of F = 3.98
En of Br = 2.96
drizzt81
quote:
Originally posted by Turbonium
K that's what I figured. But is the molecule polar? All the bonds are polar (En difference greater than or equal to 0.4). But does the fact that the Br is different that the 4 fluorides make it a difference enough to make it polar? If all 5 were fluorides, it obviously wouln't be polar.

En of P = 2.19
En of F = 3.98
En of Br = 2.96


i am NOT the authority on this, but i'd say it is. If you think about it:
You have this lonely Br atom on one end, which isn't all that EN, then these four MONSTERS of EN-ity on the other side, who pull like some crazy mofo's on those e-'s?

anyway, ask someone who knows their stuff, it's been 2 1/2 years for me.. i can tell you all about silicon crystals though.. if you care to know ;)
blazed it
gibberish.... LOL


god i hate chemistry
Mako
Yes it is polar, when thinking about polarity, think vectors.

Edit: sorry i didn't pay attention to the whole molecule :D. So yeah it will because, there are 4 fluorines (most electronegative F = 4.0) while bromine is less electronegative. The fluorines will pull electrons towards themselves from other atoms, making P and ultimately Br (which are both less electronegative) slightly more positive, giving a small charge separation.
drizzt81
quote:
Originally posted by Mako
Yes it is polar, when thinking about polarity, think vectors.

Edit: sorry i didn't pay attention to the whole molecule :D. So yeah it will because, there are 4 fluorines (most electronegative F = 4.0) while bromine is less electronegative. The fluorines will pull electrons towards themselves from other atoms, making P and ultimately Br (which are both less electronegative) slightly more positive, giving a small charge separation.


but the other atoms are Fluorine, which is even more EN.

n/m ;)
Mako
quote:
Originally posted by drizzt81
but the other atoms are Fluorine, which is even more EN.

n/m ;)


err.. you didn't read my edit? :p
Mako
quote:
Originally posted by Mako
err.. you didn't read my edit? :p


ohh n/m lol!
drizzt81
quote:
Originally posted by Mako
ohh n/m lol!
i gather you did not read mine ;P

Mako
quote:
Originally posted by drizzt81
i gather you did not read mine ;P


:whip: :toothless :whip:
zarathustra
Looks polar to me, although Chem was a looooong time ago.
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